The AT-AT walkers varied form in size and scale and paint techniques, they tend to have a lot of stains rather than solid colours, thinning down paint is a good way of recreating the look but makes it harder to establish exact colours. Below is a basic set that should get you through most AT-AT.
Set Contains
AX-033 DS Surface Grey
AX-007 1975 SP Lettering Grey
AX-009 1975 SP Lark Light Grey
AX-008 1975 SP Lark Dark Grey
AX-003 Dark Grime
Other recomendations are
Rust
Weathered black
Roof Brown
Foundation